期刊
EUROPEAN POLYMER JOURNAL
卷 112, 期 -, 页码 581-590出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.eurpolymj.2018.10.020
关键词
Anion exchange membranes; Crown ether; Polymer; Conductivity; Fuel cell
资金
- Scientific Research Fund of Liaoning Provincial Education Department, China [L2013153]
- Fundamental Research Funds for the Doctoral of Liaoning Provincial Natural Science Foundation, China [20141126]
- Science and Technology Development Fund Project of Fushun city of China [20141115]
4-formyl dibenzo-18-crown-6 (FDB18C6) was synthesized through dibenzo-18-crown-6 (DB18C6), and it was added into polyvinyl alcohol (PVA) through acetal reaction to form a new type of membrane (F-X%-P). Then the F-X%-P membranes were immersed into the KOH solution to prepare F-X%-P-K membranes, which through the complexation of crown ion on K+. The complex crown ether cation was successfully applied as anion conducting groups. The characterization and experimental results showed that F-X%-P-K membranes had already successfully synthesized, and possess better anionic conductivity and alkali resistance stability compared with other anion exchange membranes (AEMs). The water uptake and swelling ratio of F-20%-P-K membrane was reduced to 25.0% and 14.5%, separately, suppressed effectively the excessive swelling of PVA. And the dimensional stability of F-20%-P-K was 21.1%, which reflected excellent membrane stability. In addition, especially outstanding performance was the anionic conductivity of F-X%-P-K membranes increased from 7.63 mS.cm(-1) to 25.32 mS.cm(-1) at 70 degrees C, which confirmed excellent anionic conductive ability. After alkali treatment of preparing membranes, the conductivity degradation rate is less than 8.6% reflected superb alkali resistance. The aforementioned results defined that the F-X%-P-K membranes comply with the requirements in the anion exchange membrane fuel cell.
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