期刊
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY
卷 -, 期 27, 页码 3203-3209出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejic.201801486
关键词
Pincer complexes; Iridium; Palladium; Transfer hydrogenation; Homogeneous catalysis
资金
- Israel Science Foundation (ISF) [917/15, 1384/13]
- RUDN University Program 5-100
A comparative study on the chemoselective transfer hydrogenation of nitroarenes to anilines and related processes using FA as the hydrogen source is described; these processes are catalyzed by a series of pincer catalysts equipped with different functional groups in the secondary coordination sphere. Some new (4 and 5) as well as previously reported (1-3) catalysts belonging to the family of bifunctional PC(sp(3))P pincer complexes were employed in this study The reported compounds exhibited remarkably different catalytic activity behavior, depending on the nature of the functional groups. Transfer hydrogenation of nitrobenzene with FA as a hydrogen source was probed using iridium complexes 3 or 4 as a catalyst. Under the same conditions, the analogous palladium complex was found to be useful for the selective amidation of aniline with light carboxylic acids.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据