Lab-scale investigation of the ability of Polar Organic Chemical Integrative Sampler to catch short pesticide contamination peaks

In this lab-scale study, the POCIS capacity to integrate short contamination peaks of variable intensity and duration was evaluated. POCIS were immersed for 14 days in tanks filled with tap water and spiked at different concentrations with 12 pesticides of various polarities (log K (ow) = 1.1-4.7) and classes (herbicides, fungicides, and insecticides). Concentrations were kept relatively constant at 1 mu g L (-1) and 5 mu g L (-1) , respectively, in two background exposure tanks. Three contamination peaks of increasing intensity and decreasing duration were simulated (10 mu g L (-1) for 24 h, 40 mu g L (-1) for 6 h, and 60 mu g L (-1) for 1 h). This lab-scale study demonstrated that ten moderately polar compounds (2 < log K (ow) < 4) showed a linear uptake, as observed in previous studies, while a non-linear model fits the data of the two most polar pesticides (log K (ow) < 2). Depending on chemical polarity, some compounds exhibited a burst effect or lag effect during the first 3 days of exposure. After 14 days of exposure, contamination peaks appeared integrated for seven compounds, showing the ability of POCIS to catch very short pollution events and to provide acceptable time-weighted average concentration estimates under laboratory-controlled conditions.

Automated summary

This lab-scale study evaluates the ability of POCIS to integrate short contamination peaks of variable intensity and duration. It demonstrates that POCIS can capture very short pollution events and provide acceptable time-weighted average concentration estimates under laboratory-controlled conditions.