期刊
ENVIRONMENTAL PROGRESS & SUSTAINABLE ENERGY
卷 38, 期 -, 页码 S288-S297出版社
WILEY
DOI: 10.1002/ep.13013
关键词
Adsorption; Chitin; Magnetic nanoparticles; Heavy metals; Kinetics
类别
资金
- DST-INSPIRE, New Delhi, India
In this article, we described one-pot synthesis of magnetite-coated chitin (MCC) and its adsorption performance towards Pb(II) and Cd(II) ions. MCC was characterized using Fourier transform infrared, scanning electron microscope, energy dispersive X-ray analyzer, atomic force microscope, X-ray diffraction, and Brunauer-Emmett-Teller analysis. After the inclusion of magnetic nanoparticles to the chitin matrix, chitin showed increased surface area from 2.06 to 19.658 m(2) g(-1) and thus resulted in enhanced adsorption of Pb(II) and Cd(II) ions with the maximum adsorption capacity of 54.43 and 53.13 mg g(-1), respectively. Electrostatic adsorption and complexation mechanism has driven the adsorption process. Subsequently, adsorption study results revealed the spontaneous and endothermic nature of the adsorption process. The adsorption process was well described by the Freundlich isotherm and pseudo-second-order kinetic model. Moreover, field trial analysis revealed that MCC could be effectively used to remove Pb(II) and Cd(II) ions from field water. (c) 2018 American Institute of Chemical Engineers Environ Prog, 38: S288-S297, 2019
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