期刊
ELECTROCHIMICA ACTA
卷 293, 期 -, 页码 97-104出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.electacta.2018.10.010
关键词
Na-ion battery; VO2 (A) nanowire; VO2 (A)/graphene composite; Battery cathode material; Cycle stability
资金
- National Natural Science Foundation of China, China [51572027, 51372024]
- Key Project of Chinese Ministry of Education [313007]
Intercalation/deintercalation of large size Na ion leads to serious electrode materials fragmentation that would be the main reason of Na-ion battery capacity fading. Herein, we reported a Na-ion battery cathode material composed of layer-structured VO2 (A) nanowires wrapped with graphene. The VO2 (A)/graphene nanostructure which effectively suppressed pulverization of VO2 (A) nanowires during cyclic charging and discharging exhibited prominent cycle stability and high specific capacity. A reversible capacity of 115 mA h g(-1) was retained over 100 cycles at a high current density of 100 mA g(-1). Comparing to the electrochemical performance of other vanadium oxides, VO2 (A)/graphene demonstrates a potential cathode material for Na-ion batteries. (c) 2018 Elsevier Ltd. All rights reserved.
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