Evidence for magma-evaporite interactions during the emplacement of the Central Atlantic Magmatic Province (CAMP) in Brazil

Mafic sills of the Central Atlantic Magmatic Province (CAMP) in Brazil are temporally linked to the end-Triassic extinction (ETE), one of the largest mass extinctions of the Phanerozoic. The sills were emplaced into the volatile-rich sedimentary rocks of the Amazonas and Solimoes basins in northern Brazil. Here we present a new geochemical study of 26 dolerite samples from 6 deep boreholes in the Brazilian basins, including whole-rock major and trace elements, whole-rock Sr-Nd isotopes and detailed biotite mineral chemistry. The bulk of the dolerites are characterized by phenocrysts of clinopyroxene and plagioclase in subophitic to intergranular textures, Fe-Ti oxides, and rare olivine and orthopyroxene. A different mineralogical assemblage (microphenocrysts of alkali-feldspar, quartz, biotite and apatite) is found in small independent domains, localized within the framework of coarser plagioclase and clinopyroxene laths. These fine-grained evolved domains crystallized in late-stage, evolved melt pockets in the interstitial spaces between earlier crystallized coarser grained crystals. The majority of the studied dolerites are generally evolved tholeiitic basalts and basaltic andesites with low TiO2 concentrations (<2.0 wt.%). Four samples have high TiO2 concentrations (>2.0 wt.%), and are found in the eastern part of the Amazonas Basin. Whole-rock major and trace element and Sr-Nd isotope geochemistry of both low and high-Ti sills is similar to that of previously published CAMP rocks from the two magma types. Low-Ti sills show enriched isotopic signatures (Nd-143/Nd-144(201Ma) 0.51215 to 0.51244; Sr-87/Sr-86(201Ma) 0.70568 to 0.70756), coupled with crustal-like characteristics in the incompatible element patters (e.g. depletion in Nb and Ta). Unaltered high-Ti samples show more depleted isotopic signatures (Nd-143/Nd-144(201Ma) 0.51260 to 0.51262; Sr-87/Sr-86(201Ma) 0.70363 to 0.70398). Low-Ti dolerites from both the Amazonas and Solimoes basins contain biotite with extremely high Cl concentrations (up to 4.7 wt.%). We show that there is a strong correlation between host-rock lithology and Cl concentrations in biotite from the dolerites, and interpret this to reflect large-scale crustal contamination of the low-Ti magmas by halite rich evaporites. Our findings support the hypothesis that sill-evaporite interactions increased volatile release during the emplacement of CAMP. This strengthens the case for active involvement of this LIP in the end-Triassic crisis, and suggests that the sub-volcanic part of a LIP can be of major importance in driving climate change and mass extinctions. (C) 2018 Elsevier B.V. All rights reserved.