期刊
COORDINATION CHEMISTRY REVIEWS
卷 378, 期 -, 页码 310-332出版社
ELSEVIER SCIENCE SA
DOI: 10.1016/j.ccr.2017.10.028
关键词
Metal-organic framework; Host-guest interactions; Molecular recognition; Liquid-phase
资金
- National Natural Science Foundation of China [51472217, 51432001, 51632008, 51772268, U1609219]
- Zhejiang Provincial Natural Science Foundation of China [LZ15E020001]
Metal-organic frameworks (MOFs), which are constructed from metal ions/clusters with organic linkers, are in a stage from fundamentals to applications. The application of MOFs in liquid-phase adsorption/separation is one of the most significant headways in the environment and chemistry. Concerning tunable porosity, multiple functional sites and devisable host-guest interactions, goal-directed designs lead to task-specific MOFs and are requisite to perform precise molecular recognition in liquid-phase adsorption/separation. In this review, we give insights into the goal-directed design strategies of organic linkers and metal clusters for the elaboration of task-specific MOFs with targeting effects and high recognition capability, as well as the related progress of MOF-derived membranes. In addition, we put forward the cooperation of different recognition mechanisms to achieve high adsorption/separation performance. At the end, we address the challenges in these fields and propose the prospects and possible evolution for future development. (C) 2017 Elsevier B.V. All rights reserved.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据