期刊
COMPTES RENDUS CHIMIE
卷 21, 期 12, 页码 1075-1094出版社
centre Mersenne pour ldition scientifique ouverte
DOI: 10.1016/j.crci.2018.02.011
关键词
Spin crossover (SCO); Optical spectra; LIESST; Relaxation studies; Ultrafast spectroscopy
资金
- Aquitaine Region
- CNRS
- University of Bordeaux
- ANR
This article overviews the different light-induced spin-crossover processes that are induced using ligand photoreaction, photothermal effects, or optical absorption of the center metallic ion. A particular attention is drawn on the light-induced excited spin-state trapping effect, the most studied phenomenon, by discussing the recent developments in terms of description of the initial photoswitching process and the mechanisms developing at different time scales, as well as the lifetime of the photoinduced state. (C) 2018 Published by Elsevier Masson SAS on behalf of Academie des sciences.
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