4.8 Article

Manganese-Catalyzed Multicomponent Synthesis of Pyrroles through Acceptorless Dehydrogenation Hydrogen Autotransfer Catalysis: Experiment and Computation

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CHEMSUSCHEM
卷 12, 期 13, 页码 3083-3088

出版社

WILEY-V C H VERLAG GMBH
DOI: 10.1002/cssc.201802416

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acceptorless dehydrogenation; alcohols; base metals; heterocycles; hydrogen autotransfer

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A new base metal catalyzed sustainable multicomponent synthesis of pyrroles from readily available substrates is reported. The developed protocol utilizes an air- and moisture-stable catalyst system and enables the replacement of themutagenic alpha-haloketones with readily abundant 1,2-diols. Moreover, the presented method is catalytic in base and the sole byproducts of this transformation are water and hydrogen gas. Experimental and computational mechanistic studies indicate that the reaction takes place through a combined acceptorless dehydrogenation hydrogen autotransfer methodology.

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