期刊
CHEMISTRY-AN ASIAN JOURNAL
卷 14, 期 2, 页码 278-285出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/asia.201801594
关键词
electrocatalysis; hydrogen evolution reaction; molybdenum disulfide; phase engineering; photocatalysis
资金
- Ministry of Education, Culture, Sports, Science and Technology (MEXT) of Japan [26620194, 26220911]
- MEXT program, Japan
- Grants-in-Aid for Scientific Research [26620194] Funding Source: KAKEN
Molybdenum disulfide (MoS2) has been regarded as a favorable photocatalytic co-catalyst and efficient hydrogen evolution reaction (HER) electrocatalyst alternative to expensive noble-metals catalysts, owing to earth-abundance, proper band gap, high surface area, and fast electron transfer ability. In order to achieve a higher catalytic efficiency, defects strategies such as phase engineering and vacancy introduction are considered as promising methods for natural 2H-MoS2 to increase its active sites and promote electron transfer rate. In this study, we report a new two-step defect engineering process to generate vacancies-rich hybrid-phase MoS2 and to introduce Ru particles at the same time, which includes hydrothermal reaction and a subsequent hydrogen reduction. Compositional and structural properties of the synthesized defects-rich MoS2 are investigated by XRD, XPS, XAFS and Raman measurements, and the electrochemical hydrogen evolution reaction performance, as well as photocatalytic hydrogen evolution performance in the ammonia borane dehydrogenation are evaluated. Both catalytic activities are boosted with the increase of defects concentrations in MoS2, which ascertains that the defects engineering is a promising route to promote catalytic performance of MoS2.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据