期刊
CHEMISTRY-A EUROPEAN JOURNAL
卷 24, 期 70, 页码 18618-18622出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.201805129
关键词
ferrocenium; fluorescence; oxidation; phosphine; photosensitizer
资金
- CREST, JST [JPMJCR1541]
- JSPS [JN17K05803, JP16KT0160, JP17H01201, JP15H05798, JP18K19093]
- MEXT
Stoichiometric oxidation of phosphines with water and ferrocenium(III) cation as the oxygen atom source and the oxidizing reagent, respectively, was achieved in acetonitrile under visible-light irradiation by using 2,6-lutidine as the proton acceptor. The reaction required light irradiation, under which fluorescence was observed for the acetonitrile solution of the ferrocenium(III) cation.
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