期刊
CHEMISTRY-A EUROPEAN JOURNAL
卷 25, 期 18, 页码 4590-4647出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.201804225
关键词
crystal engineering; electron transfer; liquid crystals; metal-organic frameworks; porphyrins
资金
- Science Foundation Ireland [SFI IvP 13/IA/1894]
- Irish Research Council [GOIPG/2015/3700]
- Irish Research Council (IRC) [GOIPG/2015/3700] Funding Source: Irish Research Council (IRC)
Nonconjugated hydrocarbons, like bicyclo[1.1.1]-pentane, bicyclo[2.2.2]octane, triptycene, and cubane are a unique class of rigid linkers. Due to their similarity in size and shape they are useful mimics of classic benzene moieties in drugs, so-called bioisosteres. Moreover, they also fulfill an important role in material sciences as linear linkers, in order to arrange various functionalities in a defined spatial manner. In this Review article, recent developments and usages of these special, rectilinear systems are discussed. Furthermore, we focus on covalently linked, nonconjugated linear arrangements and discuss the physical and chemical properties and differences of individual linkers, as well as their application in material and medicinal sciences.
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