期刊
CHEMISTRY-A EUROPEAN JOURNAL
卷 25, 期 1, 页码 238-245出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.201804811
关键词
amine-boranes; catalysis; cobalt; dehydrogenation; transfer hydrogenation
资金
- Fonds der Chemischen Industrie
- Deutsche Forschungsgemeinschaft [JA 1107/6-1, WO 1496/6-1, DFG INST 269/595]
Anionic alpha-diimine cobalt complexes, such as [K(thf)(1.5){((Dipp)BIAN)Co(eta(4)-cod)}] (1; Dipp=2,6-diisopropylphenyl, cod=1,5-cyclooctadiene), catalyze the dehydrogenation of several amine-boranes. Based on the excellent catalytic properties, an especially effective transfer hydrogenation protocol for challenging olefins, imines, and N-heteroarenes was developed. NH3BH3 was used as a dihydrogen surrogate, which transferred up to two equivalents of H-2 per NH3BH3. Detailed spectroscopic and mechanistic studies are presented, which document the rate determination by acidic protons in the amine-borane.
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