期刊
CHEMISTRY-A EUROPEAN JOURNAL
卷 24, 期 72, 页码 19152-19155出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.201804076
关键词
gas storage; magnetism; metallamacrocycle; metal-organic frameworks; microporous materials
资金
- National Natural Science Foundation of China [21873018, 21573036, 21274017]
- Foundation of the Education Department of Jilin Province [111099108]
- Jilin Provincial Research Center of Advanced Energy Materials (Northeast Normal University)
A stable hex-type metal-organic framework (MOF, WMOF-1) was constructed by nano-sized [Mn-18(II)] metallamacrocycle secondary building unit, being the one with the highest nuclearity of manganese wheel-like node in the microporous MOF. WMOF-1 displays an effective gas adsorption and the antiferromagnetic behavior.
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