期刊
CHEMISTRY-A EUROPEAN JOURNAL
卷 25, 期 12, 页码 3000-3004出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.201806373
关键词
amination; anthranil; annulation; N-PAHs; rhodium; step-economic synthesis
资金
- CSIR, India [02(0323)/17/EMR-II]
- UGC, India
- DST, India [SR/FST/CSII-026/2013]
An efficient pot-economic and step-economic Rh-III-catalyzed site-selective direct amination/annulation strategy was developed for the synthesis of benzophenanthroline derivatives using quinoline N-oxides and anthranils. The method was further extended to the synthesis of nitrogen-containing extended -conjugated benzophenanthrolinone derivatives. Late-stage functionalizations of cinchonidine and cinchophen derivatives and synthesis of a bioactive quinolino-indole were achieved.
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