期刊
CHEMISTRY LETTERS
卷 48, 期 3, 页码 230-233出版社
CHEMICAL SOC JAPAN
DOI: 10.1246/cl.180930
关键词
N-Heterocyclic carbenes (NHCs); Phosphine oxides; Alkali metals
资金
- JSPS KAKENHI [JP18K14219, JP15H05803]
A reaction between an N-phosphine oxide-substituted imidazolylidene (PoxIm) and MOTf (M = Li or Na) in THF afforded the complexes [(PoxIm)(x)(MOTf)(y)(THF)(z)] through the coordination of the N-phosphoryl group to Na+ or Li+, which was unambiguously confirmed by C-13 and (PNMR)-P-31 spectroscopy and single-crystal X-ray diffraction analyses. These measurements confirmed that the carbene moieties in these complexes remain intact. In solution, PoxIm and MOTf might form the complexes in a 3:2 ratio (i.e., x = 3, y = 2), while ratios of 1:1 (M = Li; x = 1, y = 1) and 2:1 (M = Na; x = 2, y = 1) were observed in the solid state.
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