期刊
CHEMICAL ENGINEERING JOURNAL
卷 356, 期 -, 页码 178-189出版社
ELSEVIER SCIENCE SA
DOI: 10.1016/j.cej.2018.08.216
关键词
Persulfate; CuO; Non-radical activation; Selective removal; Crystal facet effect
资金
- National Natural Science Foundation of China [51572089, U1701243]
- National Key Research and Development Program of China, China [2016YFC0400708]
- Natural Science Foundation of Guangdong Province, China [2015A030313232]
- Foundation of Science and Technology Planning Project of Guangdong Province, China [2016A050502007]
- Foundation of Science and Technology Planning Project of Guangzhou, China [201804010398]
- Funds of State Key Laboratory of Pulp and Paper Engineering [201837]
Non-radical activation of persulfate by CuO to degrade chlorinated organic pollutants has been studied. Currently, reduced graphene oxide modified spindle-like CuO (CuO/rGO, no preferential exposed crystal facet) and CuO with preferential exposed crystal facet (0 0 1) (sheet-like CuO) has been prepared to improve the performance of persulfate activation. Results showed that CuO/rGO-persulfate system and sheet-like CuO-persulfate system exhibited much better 2,4,6-trichlorophenol (TCP) removal rate than spindle-like CuO-persulfate system. The formation of Cu-O-C bond between CuO and rGO enhanced the persulfate activation by CuO. On the other hand, CuO showed crystal facet effect on persulfate activation, and the crystal facet (0 0 1) of CuO (all exposed atoms were Cu) were proved to be efficient for persulfate non-radical activation, revealing that Cu atom on surface was active site for persulfate activation. Furthermore, the pollutants selective removal by CuO/rGO-persulfate system has been found. 4-chloroaniline was most easily degraded, followed by 2,4,6-trichlorophenol, 2,4-dichlorophenol and 4-chlorophenol, under acidic, neutral and weak basic condition (pH 3-9). What's more, pollutants with benzene ring was more reactive than that with double bond of carbon in the system.
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