期刊
CHEMICAL ENGINEERING COMMUNICATIONS
卷 206, 期 6, 页码 789-803出版社
TAYLOR & FRANCIS INC
DOI: 10.1080/00986445.2018.1527319
关键词
Adsorption; Corrosion; Gasometry; Gravimetry; Hydrogen production; Impedance measurements; Inhibition; Potentiodynamic; Thermometry
资金
- deanship of science research at Northern Border University, Arar, K.S.A. [Sci-2017-1-7-F-7030]
Two of dihydropyridine derivatives, namely, 4,6-dimethyl-2-oxo-1,2-dihydropyridine-3-carbonitrile (DPCN) and 4,6-dimethyl-2-oxo-1,2-dihydropyridine-3-carboxamide (DPCA) were evaluated as controllers for H-2 production during the dissolution of Zn in dilute HCl. Different chemical (thermometry, gravimetry, and gasometry) and electrochemical (potentiodynamic polarization and impedance) techniques were used. SEM and optical profilometry surface investigations for some corroded and un-corroded Zn samples were carried out to describe the Zn surface during the dissolution process. The rate of H-2 production was found to increase with the immersion time and temperature and was lowered by the inhibitor. The potentiodynamic data proved that DPCN and DPCA inhibit the dissolution of Zn according to a mixed-type mechanism.
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