4.6 Review

Aqueous biphasic hydroformylation of olefins: From classical phosphine-containing systems to emerging strategies based on water-soluble nonphosphine ligands

期刊

CATALYSIS REVIEWS-SCIENCE AND ENGINEERING
卷 61, 期 1, 页码 111-133

出版社

TAYLOR & FRANCIS INC
DOI: 10.1080/01614940.2018.1541781

关键词

Aqueous biphasic; higher olefins; water-soluble; nonphosphine ligands

资金

  1. National Research Foundation of South Africa (NRF) [105559, 95517, 99269]
  2. SASOL
  3. Department of Science and Technology and National Research Foundation of South Africa (NRF-DST) Centre of Excellence in Catalysis (c*change) under: [UJ-OLE] projects
  4. University of Johannesburg Centre for Synthesis and Catalysis

向作者/读者索取更多资源

This review provides an overview of recent developments in the area of aqueous biphasic hydroformylation of higher olefins using metal catalysts and surfactants, cosolvents, thermoregulated ligands, cyclodextrins, and most importantly emerging water-soluble nonphosphine ligands. Water-soluble phosphine ligands have been widely explored for aqueous biphasic hydroformylation; however, phosphines are generally expensive and are prone to oxidation hence the recent interest in exploring other ligands. Various approaches have been used to introduce hydrophilicity to the ligands. The catalytic activity of monometallic and heterobimetallic systems containing nonphosphine ligands in aqueous biphasic media is emphasized in this review.

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