期刊
BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN
卷 92, 期 1, 页码 97-104出版社
CHEMICAL SOC JAPAN
DOI: 10.1246/bcsj.20180261
关键词
Perfluoroalkyl; Low-molecular-weight organic gelators; Rheology
资金
- JSPS [17K14452]
- Grants-in-Aid for Scientific Research [17K14452] Funding Source: KAKEN
Novel perfluoroalkyl gelators without hydrogen bonds-bis(2,2,3,3,4,4,5,5,6,6,7,7,8,8,8-pentadecafluorooctyl) iso-phthalate (1m), bis(2,2,3,3,4,4,5,5,6,6,7,7,8,8,8-pentadecafluorooctyl) terephthalate (1p), and tris-(2,2,3,3,4,4,5,5,6,6,7,7,8,8,8-pentadecafluorooctyl) benzene-1,3,5-tricarboxylate (2)-were synthesized. Their molecular structures were investigated by density functional theory calculations at the B3LYP/cc-pVDZ level. The gelation abilities of 1m, 1p, and 2 were examined and compared to their normal octyl homologues 1m', 1p', and 2'. None of the gelators could be gelated in common organic solvents, but gelated well in fluorinated solvents.
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