期刊
BEILSTEIN JOURNAL OF ORGANIC CHEMISTRY
卷 14, 期 -, 页码 2568-2571出版社
BEILSTEIN-INSTITUT
DOI: 10.3762/bjoc.14.233
关键词
carboxonium ion; glycosylium ion; oxacarbenium ion; oxocarbenium ion; oxycarbenium ion
The nomenclature of cations (RC)-C-1(=(O+R3))R-2 (R-1,R-2,R-3 = H or organyl) has been examined and shown to be in a state of immeasurable confusion: a pragmatic recommendation is made that the generic term carbonylonium ions should be adopted for these intermediates, which comprises the terms aldehydium (R-1 = H, R-2, R-3 = H or organyl) and ketonium ions (R-1, R-2 = organyl, R-3 =H or organyl) for the corresponding aldehyde-and ketone-based intermediates, respectively.
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