期刊
APPLIED ORGANOMETALLIC CHEMISTRY
卷 33, 期 3, 页码 -出版社
WILEY
DOI: 10.1002/aoc.4775
关键词
anthranil; Catellani reaction; nitrene; norbornene; palladium
资金
- National Natural Science Foundation of China [21572203]
- Zhejiang Provincial Natural Science Foundation [LZ16B020001]
Catellani reactions of aryl iodides allow the double functionalization at the ortho and ipso positions in one pot. Catellani reactions involving a nitrene intermediate are not yet known. In this paper, a few palladium amino complexes were prepared from PdCl2, anthranil and iodoarenes, and their structures were determined by X-ray single-crystal diffraction. These complexes are supported by a pincer C,N,O tridentate ligand forming fused six-membered palladacycles. The high stability of the palladium complexes inhibits their reductive elimination.
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