期刊
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
卷 58, 期 2, 页码 592-595出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201811782
关键词
allyl complexes; boron; homogeneous catalysis; palladium
资金
- NIH [GM-R35-127140]
Organoboron ate complexes undergo a net vinyl insertion reaction to give 1,1-disubstituted alkenyl boronic esters when treated with stoichiometric allyl acetate and a palladium catalyst. Reactions that employ vinyllithium afforded good to excellent yields after one hour, while reactions that employ vinylmagnesium chloride furnished modest to good yields after 18 hours.
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