期刊
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
卷 57, 期 51, 页码 16832-16836出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201810782
关键词
borylation; iodides; metal-free synthesis; radical process
资金
- European Research Council (ERC Advanced Grant) [692640]
- European Research Council (ERC) [692640] Funding Source: European Research Council (ERC)
A metal-free radical borylation of alkyl and aryl iodides with bis(catecholato)diboron (B(2)cat(2)) as the boron source under mild conditions is introduced. The borylation reaction is operationally easy to conduct and shows high functional group tolerance and broad substrate scope. Radical clock experiments and density functional theory calculations provide insights into the mechanism and rate constants for C-radical borylation with B(2)cat(2) are disclosed.
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