期刊
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
卷 57, 期 52, 页码 17130-17134出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201810925
关键词
chiral resolution; chirality; homochiral; membrane separation; metal-organic frameworks
资金
- Australian Research Council [DP170102964, DE170100006]
- Deakin University's Advanced Facility
- Australian Research Council [DE170100006] Funding Source: Australian Research Council
Homochiral metal-organic frameworks (MOFs) have gained much attention because of their chiral properties and disposition for chiral separation. However, the fabrication of high-quality homochiral MOF membranes remains challenging because of the difficulty in controlling growth of MOF membranes with chiral functionalities. A homochiral zeolitic imidazolate framework-8 (ZIF-8) membrane is reported for efficient chiral separation. The membrane is synthesized by incorporating a natural amino acid, L-histidine (L-His), into the framework of ZIF-8. The homochiral L-His-ZIF-8 membrane exhibits a good selectivity for the R-enantiomer of 1-phenylethanol over the S-enantiomer, showing a high enantiomeric excess value up to 76%.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据