期刊
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
卷 57, 期 48, 页码 15762-15766出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201809929
关键词
amides; C-H activation; borylation; iridium; noncovalent interactions
资金
- DST-SERB [SB/S2/RJN-45/2013, SB/FT/CS-141/2014]
- CSIR
- UGC
A new concept for the meta-selective borylation of aromatic amides is described. It has been demonstrated that while esters gave para borylations, amides lead to meta borylations. For achieving high meta selectivity, an L-shaped bifunctional ligand has been employed and engages in an O center dot center dot center dot K noncovalent interaction with the oxygen atom of the moderately distorted amide carbonyl group. This interaction provides exceptional control for meta C-H activation/borylation.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据