期刊
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
卷 58, 期 34, 页码 11586-11598出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201813523
关键词
excited-state Pd complex; palladium; photochemistry; radical reactions
Palladium catalysis induced by visible light is an emerging field of catalysis. In contrast to classical reactions catalyzed by Pd complexes in the ground state, which mostly proceed through two-electron redox processes, the mechanisms of these new methods based on photoexcited Pd complexes usually operate through transfer of a single electron. Such processes lead to putative hybrid Pd/radical species, which exhibit both radical and classical Pd-type reactivity. This Minireview highlights the recent progress in this rapidly growing area.
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