期刊
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
卷 58, 期 16, 页码 5226-5231出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201814729
关键词
biomimetic catalysis; hydrophobicity; metal-organic frameworks; photochemistry; photosynthesis
资金
- NSFC [21622104, 21871141, 21871142, 21701085]
- NSF of Jiangsu Province of China [SBK2017040708, BK20171032]
- Natural Science Research of Jiangsu Higher Education Institutions of China [17KJB150025]
- Priority Academic Program Development of Jiangsu Higher Education Institutions
- Foundation of Jiangsu Collaborative Innovation Center of Biomedical Functional Materials
Visible-light driven photoconversion of CO2 into energy carriers is highly important to the natural carbon balance and sustainable development. Demonstrated here is the adenine-dependent CO2 photoreduction performance in green biomimetic metal-organic frameworks. Photocatalytic results indicate that AD-MOF-2 exhibited a very high HCOOH production rate of 443.2 mu mol g(-1) h(-1) in pure aqueous solution, and is more than two times higher than that of AD-MOF-1 (179.0 mu mol g(-1) h(-1)) in acetonitrile solution. Significantly, experimental and theoretical evidence reveal that the CO2 photoreduction reaction mainly takes place at the aromatic nitrogen atom of adenine molecules through a unique o-amino-assisted activation rather than at the metal center. This work not only serves as an important case study for the development of green biomimetic photocatalysts used for artificial photosynthesis, but also proposes a new catalytic strategy for efficient CO2 photoconversion.
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