期刊
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
卷 58, 期 7, 页码 2073-2077出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201813417
关键词
2D; 2D heterojunctions; black phosphorus; hydrogen production; photocatalysis; Z-scheme
资金
- National Key R&D Program of China [2017YFC0210901, 2017YFC0210906]
- National Natural Science Foundation of China [51573122, 21722607, 21776190]
- Postgraduate Research & Practice Innovation Program of Jiangsu Province [KYCX18_2513]
- Priority Academic Program Development of Jiangsu Higher Education Institutions (PAPD)
Black phosphorus (BP), a star-shaped two-dimensional material, has attracted considerable attention owing to its unique chemical and physical properties. BP shows great potential in photocatalysis area because of its excellent optical properties; however, its applications in this field have been limited to date. Now, a Z-scheme heterojunction of 2D/2D BP/monolayer Bi2WO6 (MBWO) is fabricated by a simple and effective method. The BP/MBWO heterojunction exhibits enhanced photocatalytic performance in photocatalytic water splitting to produce H-2 and NO removal to purify air; the highest H-2 evolution rate of BP/MBWO is 21042molg(-1), is 9.15 times that of pristine MBWO and the NO removal ratio was as high as 67%. A Z-scheme photocatalytic mechanism is proposed based on monitoring of O-.(2)-, (OH)-O-., NO2, and NO3- species in the reaction. This work broadens applications of BP and highlights its promise in the treatment of environmental pollution and renewable energy issues.
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