期刊
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
卷 58, 期 5, 页码 1340-1344出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201810544
关键词
hydrogen production; long afterglow; methanol; photocatalysis; water
资金
- National Natural Science Foundation of China [21535004, 91753111, 21575082, 21507074, 21390411]
- Key Research and Development Program of Shandong Province [2018YFJH0502]
- Development plan of science and technology for Shandong Province of China [2013GGX10706]
- Shandong Province Natural Science Foundation [ZR2015BM023]
- Shandong Province Higher Educational Science and Technology Program [J13LD06]
Long afterglow materials can store and release light energy after illumination. A brick-like, micrometer-sized Sr2MgSi2O7:Eu2+, Dy3+ long-afterglow material is used for hydrogen production by the photocatalytic reforming of methanol under round-the-clock conditions for the first time, achieving a solar-to-hydrogen (STH) conversion efficiency of 5.18%. This material is one of the most efficient photocatalysts and provides the possibility of practical use on a large scale. Its remarkable photocatalytic activity is attributed to its unique carrier migration path and large number of lattice defects. These findings expand the application scope of long afterglow materials and provide a new strategy to design efficient photocatalysts by constructing trap levels that can prolong carrier lifetimes.
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