4.7 Article

Chemo-selective Rh(II)/Pd(0) Dual Catalysis: Synthesis of All-Carbon C3-Quaternary Allylic Oxindoles from N-Aryl-α-Diazo-β-Keto-Amides with Functionalized Allyl Carbonates

期刊

ADVANCED SYNTHESIS & CATALYSIS
卷 361, 期 6, 页码 1307-1312

出版社

WILEY-V C H VERLAG GMBH
DOI: 10.1002/adsc.201801346

关键词

Dual catalysis; pi-Allyl palladium complex; Rhodium-carbenoids; Quaternary carbon center; Oxindoles

资金

  1. National Natural Science Foundation of China [21402154, 21502150]
  2. Chinese Universities Scientific Fund [2452016093]
  3. Youth Training Project of Northwest AF University [2452017034, 2452016006]

向作者/读者索取更多资源

A chemo-selective Rh(II)/Pd(0) dual catalysis that promotes one-pot synthesis of C3-quaternary allylic oxindoles from N-aryl-alpha-diazo-beta-ketoamides and functionalized allyl carbonates in good to excellent yields has been developed. The efficiency of this transformation relies on the choice of Rh(II)/Pd(0) dual catalysis strategy that enabled cascade intramolecular aryl C-H insertion and allylic alkylation under mild conditions.

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