期刊
ADVANCED SYNTHESIS & CATALYSIS
卷 361, 期 6, 页码 1208-1229出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adsc.201801070
关键词
catalysis; ketene S,S-acetals; metals; synthetic methods
资金
- National Natural Science Foundation of China [21672032]
- Fundamental Research Funds for the Central Universities [2412017QD013]
The readily available ketene S,S-acetals (ketene dithioacetals) are useful building blocks for the construction of a wide range of organic molecules and natural products. This review attempts to summarize the recent advances in the field of ketene dithioacetal chemistry since 2012, especially metal-catalyzed/metal-mediated bond-forming reactions with the emphasis on the catalysts and reaction modes based on their unique structural features. Discussions on the reaction mechanisms and the applications of the developed methods in synthesis are also included with personal comments in some cases.
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