期刊
ADVANCED SYNTHESIS & CATALYSIS
卷 361, 期 2, 页码 283-288出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adsc.201801240
关键词
carbon dioxide fixation; iron; cycloaddition; homogeneous catalysis
资金
- Ministero dell'Istruzione dell'Universita e della Ricerca (MIUR, Roma, Italy)
- Universita degli Studi di Salerno [FARB 2016-ORSA165551]
A new [OSSO]-Fe(III) metallate complex was prepared and characterized. We demonstrated that such metallate is the real catalytic active species for the cycloaddition of CO2 to the epoxides, formed from the in situ reaction of the related [OSSO]-Fe(III) neutral complexes and tetrabutylammonium bromide. The metallate complex was used as a single component catalyst for the formation of cyclic organic carbonates from ten epoxides and CO2 at 1 bar pressure with good activity.
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