期刊
ADVANCED MATERIALS
卷 30, 期 50, 页码 -出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adma.201804691
关键词
cesium lead iodide; doping; light-emitting devices; perovskite nanocrystals; strontium chloride; surface passivation
类别
资金
- Natural Science Foundation of China [61675086, 61475062, 61722504, 51702115, 51772123]
- National Key Research and Development Program of China [2017YFB0403601]
- China Postdoctoral Science Foundation [2017M611319]
- National Postdoctoral Program for Innovative Talents [BX201600060]
- Special Project of the Province-University Co-constructing Program of Jilin University [SXGJXX2017-3]
- BORSF RCS, Institutional Development Award [P20GM103424]
- Research Grant Council of Hong Kong S.A.R. [CityU11337616]
A method is proposed to improve the photo/electroluminescence efficiency and stability of CsPbI3 perovskite nanocrystals (NCs) by using SrCl2 as a co-precursor. The SrCl2 is chosen as the dopant to synthesize the CsPbI3 NCs. Because the ion radius of Sr2+ (1.18 angstrom) is slightly smaller than that of Pb2+ (1.19 angstrom) ions, divalent Sr2+ cations can partly replace the Pb2+ ions in the lattice structure of perovskite NCs and cause a slight lattice contraction. At the same time, Cl- anions from SrCl2 are able to efficiently passivate surface defect states of CsPbI3 nanocrystals, thus converting nonradiative trap states to radiative states. The simultaneous Sr2+ ion doping and surface Cl- ion passivation result in the enhanced photoluminescence quantum yield (up to 84%), elongated emission lifetime, and improved stability. Sr2+-doped CsPbI3 NCs are employed to produce light-emitting devices with a high external quantum yield of 13.5%.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据