期刊
ADVANCED MATERIALS
卷 31, 期 45, 页码 -出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adma.201806090
关键词
membrane; organic liquid; porous polymer; separation; solvent stability
类别
资金
- National Key Basic Research Program of China [2014CB931801, 2016YFA0200700]
- National Natural Science Foundation of China [51472054, 21475029, 21721002, 21890381]
- Frontier Science Key Project of the Chinese Academy of Sciences [QYZDJ-SSW-SLH038]
- Instrument Developing Project of the Chinese Academy of Sciences [YZ201311]
- K. C. Wong Education Foundation
- Youth Innovation Promotion Association CAS
Membrane technology is one of the most promising technologies for separation and purification that is routinely and commercially employed in aqueous solutions. In comparison, its applications in organic solvents are severely underdeveloped mainly due to the poor stability of traditional polymer membranes in organic solvents. The emerging materials such as crosslinked polymers, covalent organic frameworks, metal-organic frameworks, conjugated microporous polymers, carbon molecular sieves, and graphene provide the solutions to address this problem. The membranes constructed with these novel materials show outstanding separation performance in regard to both high selectivity and solvent permeability, greatly pushing forward utilization of membrane technology in organic media. Here, an overview of the most important organic mixtures that need to be separated, the major separation processes adopted nowadays in organic solvents, and the recent progress in new developed membranes is provided.
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