期刊
ADVANCED MATERIALS
卷 30, 期 51, 页码 -出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adma.201804378
关键词
anode materials; sodium-ions batteries; Ti2Nb2O9; ultrathin nanosheets
类别
资金
- National Key R&D Research Program of China [2018YFB0905400]
- National Natural Science Foundation of China [51872277, 51622210, 51504139, 21573204, 21421063]
- Sofja Kovalevskaja award
- Alexander von Humboldt Foundation
- MOST [2016YFA0200602, 2018 YFA0208603]
- Fundamental Research Funds for the Central Universities [WK3430000004]
- Max Planck Society
Sodium-ion batteries are emerging as promising candidates for grid energy storage because of the abundant sodium resources and low cost. However, the identification and development of suitable anode materials is far from being satisfactory. Here, it is demonstrated that the Ti2Nb2O9 nanosheets with tunnel structure can be used as suitable anode materials for sodium-ion batteries. Ti2Nb2O9 nanosheets are synthesized by liquid exfoliation combined with topotactic dehydration, delivering a high reversible capacity of 250 mAh g(-1) at 50 mA g(-1) at a suitable average voltage of approximate to 0.7 V. It is found that a low energy diffusion barrier, enlarged interlayer spacing, and exceptional nanoporosity together give rise to high rate performance characterized by pseudocapacitive behavior. The observed high reversible capacity, excellent rate capability, and good cyclability of Ti2Nb2O9 nanosheets make this material competitive when compared to other sodium insertion anode materials.
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