期刊
ADVANCED FUNCTIONAL MATERIALS
卷 29, 期 6, 页码 -出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adfm.201807377
关键词
composite anodes; nanoparticles; one-pot; rambutan-like hybrid hollow structure; sodium-ion batteries
类别
资金
- National Natural Science Foundation of China [51772154, 51772152, 51572129]
- International S&T Cooperation Program of China [2016YFE0111500]
- Natural Science Foundation of Jiangsu Province [BK20170036, BK20180475]
- Fundamental Research Funds for the Central Universities [30915011204, 30917011345]
Transition metal oxides, possessing high theoretical specific capacities, are promising anode materials for sodium-ion batteries. However, the sluggish sodiation/desodiation kinetics and poor structural stability restrict their electrochemical performance. To achieve high and fast Na storage capability, in this work, rambutan-like hybrid hollow spheres of carbon confined Co3O4 nanoparticles are synthesized by a facile one-pot hydrothermal treatment with postannealing. The hierarchy hollow structure with ultrafine Co3O4 nanoparticles embedded in the continuous carbon matrix enables greatly enhanced structural stability and fast electrode kinetics. When tested in sodium-ion batteries, the hollow structured composite electrode exhibits an outstandingly high reversible specific capacity of 712 mAh g(-1) at a current density of 0.1 A g(-1), and retains a capacity of 223 mAh g(-1) even at a large current density of 5 A g(-1). Besides the superior Na storage capability, good cycle performance is demonstrated for the composite electrode with 74.5% capacity retention after 500 cycles, suggesting promising application in advanced sodium-ion batteries.
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