期刊
ADVANCED FUNCTIONAL MATERIALS
卷 29, 期 6, 页码 -出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adfm.201807688
关键词
antifluorite; conductivity; defect chemistry; Li2S; lithium sulfide
Lithium sulfide is a functional material of great importance for battery research, since it is the discharge product in Li-S cathodes and a frequent component of anode passivation layers. In both cases, transport of charge carriers in Li2S is critical for performance. The exploration of charge carrier chemistry in such a simple binary compound is also of fundamental scientific interest. For that purpose, impedance spectroscopy and electromotive force measurements are performed over a broad range of temperatures and doping conditions. The results indicate predominant ion conduction and can be quantitatively explained by a defect chemical model based on Frenkel disorder and vacancy-dopant association. Mobilities and migration barriers for both vacancy and interstitial defects are deduced. The thermodynamic and kinetic parameters derived for Li+ transport in antifluorite Li2S show remarkable agreement with the analogous parameters for F- transport in fluorite compounds such as BaF2, thereby improving the structural understanding of charge carrier chemistry in such compounds. An application of these results to passivation layers in solid state batteries is also discussed.
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