期刊
ACS APPLIED MATERIALS & INTERFACES
卷 10, 期 49, 页码 42372-42379出版社
AMER CHEMICAL SOC
DOI: 10.1021/acsami.8b15604
关键词
lithium ion battery; transition metal oxides; double carbon coating; Co3O4; electrochemical performance
资金
- National Natural Science Foundation of China (NSFC) [51703087, 21805117]
- Jiangsu Province Science Foundation for Youths [BK20180209]
- Priority Academic Program Development Fund of Jiangsu Higher Education Institutions
Improving the structural stability and the electron/ion diffusion rate across whole electrode particles is crucial for transition metal oxides as next-generation anodic materials in lithium-ion batteries. Herein, we report a novel structure of double carbon-coated Co3O4 cross-linked composite, where the Co3O4 nanoparticle is in situ covered by nitrogen-doped carbon and further connected by carbon nanotubes (Co3O4 NP@NC@CNTs). This double carbon-coated Co3O4 NP@NC@CNTs framework not only endows a porous structure that can effectively accommodate the volume changes of Co3O4, but also provides multidimensional pathways for electronic/ionic diffusion in and among the Co3O4 NPs. Electrochemical kinetics investigation reveals a decreased energy barrier for electron/ion transport in the Co304 NP@NC@CNT5, compared with the single carbon-coated Co3O4 NP@NC. As expected, the Co3O4 NP@NC@CNT electrode exhibits unprecedented lithium storage performance, with a high reversible capacity of 1017 mA h g(-1) after 500 cycles at 1 A g(-1), and a very good capacity retention of 75%, even after 5000 cycles at 15 A g(-1). The lithiation/delithiation process of Co3O4 NP@NC@CNTs is dominated by the pseudocapacitive behavior, resulting in excellent rate performance and durable cycle stability.
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