期刊
ACS APPLIED MATERIALS & INTERFACES
卷 10, 期 42, 页码 35671-35675出版社
AMER CHEMICAL SOC
DOI: 10.1021/acsami.8b10777
关键词
metal organic framework; copper-viologen framework; polyoxometalate cluster; crystalline material; photocatalysis; broadband solar response
资金
- program for the NSFC [21573076, 21703070]
- NSF (Guangdong) [2015A030312007]
- FRFCU [2017BQ064]
- Science and Technology Program of Guangzhou [201804010131, 201804010176]
- SRP Program
An efficient photocatalyst based on the broadband solar response molecular system was designed and constructed for pollutant degradation in near-neutral conditions via utilizing guest polyoxometalate cluster sensitized with electron deficient host network. Photoelectrochemical analysis reveals electron hole pairs are generated efficiently upon both visible and NIR light excitation. Its photocatalytic activity in the visible and NIR light regions is enhanced because of the contribution from the broad absorption of copper-viologen framework and the strong host guest interactions. This stable heterogeneous catalyst is easily recollected and regenerated without the loss of activity for the next cycle.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据