期刊
ACS APPLIED MATERIALS & INTERFACES
卷 10, 期 46, 页码 40265-40273出版社
AMER CHEMICAL SOC
DOI: 10.1021/acsami.8b13983
关键词
Cu(OH)(2)@ZIF-8; nanowire membrane; switchable superwetting; capillary effect; oil/water separation
资金
- National Natural Science Foundation of China [21771001]
- Anhui Provincial Natural Science Foundation [1708085ME120]
- Key Natural Science Research Project of the Anhui Provincial Education Department [KJ2017A007]
- Program of Anhui Scientific and Technical Leaders Reserve Candidates
- Research Fund Program of Guangdong Provincial Key Laboratory of Environmental Pollution Control and Remediation Technology [2018K11]
- open fund for Discipline Construction, Institute of Physical Science and Information Technology, Anhui University
- Scholar Program for the Outstanding Innovative Talent of College Discipline (Specialty)
Highly ordered architectures with roughness and porous surface are the key challenges toward developing smart superwetting membranes. We prepared switchable superwetting Cu(OH)(2)@ZIF-8 core/shell nanowire membranes for high-flux oil/water separation as well as simultaneous heavy-metal ions removal in one step. The well-defined Cu(OH)2@ZIF-8 core/shell nanowire grown on copper mesh with average length of ca. 15 mu m and diameter of ca. 162 nm exhibits high water contact angle (CA) of ca. 153 +/- 0.6 degrees. After modified by ethanol, the membrane holds the reverse superwettability with oil (dichloromethane as an example) CA of ca. 155 +/- 0.8 degrees underwater. The separation efficiencies of the membranes are higher than that of 97.2% with a remarkable flux rate higher than 90 000 L m(-2) h(-1) for the immiscible oil/water mixture. And the removal efficiency for Cr3+ ions at 10 ppb can arrive at 99.2 wt % in the toluene-in-water emulsion. The high performances of the smart superwetting membranes can be attributed to the interfacial capillary effects of the hierarchical Cu(OH)(2)@ZIF-8 core/shell nanostructures. This work may provide a new insight into the design of smart superwetting surfaces for oil/water separation and target adsorption in one step.
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