期刊
ROYAL SOCIETY OPEN SCIENCE
卷 5, 期 7, 页码 -出版社
ROYAL SOC
DOI: 10.1098/rsos.180757
关键词
organophosphorus pesticide; storage stability; solvent; matrix; light; temperature
资金
- National Natural Science Foundation of China [21177155]
This study was performed to determine the storage stability of organophosphorus pesticide residues in high oil content commodity matrices, peanut and soya bean. The storage conditions included different types of solvents (ethyl acetate, acetone and hexane) and corresponding extracted matrix solutions, light and temperature. It was found that three pesticides degraded quickly especially in ethyl acetate solvent. They decreased greater than 30% when stored for 3 days at -20 degrees C in ethyl acetate; the results showed that the stability could be improved in the extracted matrix solutions. Light had a slight effect for stability of phorate and fenthion, while it played an important effect for disulfoton with the exception of ethyl acetate as solvent. Even at -20 degrees C, exposure to solvents or extracted matrix solution resulted in 40.67, 96.33 and 35.07% loss of phorate, disulfoton and fenthion. Hence, it could be assumed that these three residues could be more stable at lower temperature, in the dark and in acetone or hexane extracted peanut and soya bean solutions.
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