期刊
ROYAL SOCIETY OPEN SCIENCE
卷 5, 期 7, 页码 -出版社
ROYAL SOC
DOI: 10.1098/rsos.180207
关键词
donor-acceptor Stenhouse adducts; secondary amine; polycarbonate; amine indicator
资金
- Federal Ministry of Education and Research (BMBF) within the Initiative 'Centre for Innovation Competence' Meta-ZIK [FKZ 03Z1M511, 03Z1M512]
- Optimi [FKZ: 16SV3701, FKZ 16SV5473]
- Carl Zeiss [FKZ 0563-2.8/399/1]
- Thuringian Ministry of Culture (Nanozellkulturen) [FKZ: B714-09064]
Donor-acceptor Stenhouse adducts (DASAs) are gaining attention from organic and material chemists due to their visible light-stimulated photochromic properties. In this report, we present a facile method for grafting coloured triene on polycarbonate surface, without involving any pre-treatments like plasma activation, etc. The chemoselectivity of carbonate with a primary amine and Meldrum's activated furan (MAF) with polymer bound secondary amine has been exploited to graft photoswitchable DASA on the polymer surface. Primary, secondary and tertiary amine-functionalized polycarbonate surfaces have been prepared to evaluate the reactivity of amine with MAF.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据