期刊
MATERIALS & DESIGN
卷 88, 期 -, 页码 1191-1200出版社
ELSEVIER SCI LTD
DOI: 10.1016/j.matdes.2015.09.079
关键词
Porous adsorption material; Coal slag; Preparation; Adsorption; Phenol
资金
- National Natural Science Foundation of China [21466028]
- Program for New Century Excellent Talents in University [NCET-12-1017]
- Program for Grassland Excellent Talents of Inner Mongolia Autonomous Region
- Inner Mongolia Talented People Development Fund
A new porous adsorption material (PAM) was successfully prepared from raw coal slag and characterized by several techniques, including N-2 adsorption-desorption isotherm, thermogravimetric analysis (TGA), flourier transform infrared spectroscopy (FTIR), scanning electron microscope (SEM), Transmission electron microscope (TEM) and X-ray diffraction (XRD) measurement. The preparation procedure of PAM involved two steps: (1) SiO32- chemical leaching from coal slag, and (2) preparation of the PAM. The optimum SiO32- leaching condition was confirmed at 30 mL HCl for the pretreated processes, 200 mesh particle size of coal slag, leaching temperature of 100 degrees C, reaction time of 2 h, NaOH initial concentration of 30 wt.%, and the ratio of alkaline to slag of 2:1. Under this condition, SiO32- leaching yield arrived at 39.42 wt.%, which accounted for 80.78 wt.% of the total content of SiO32 in coal slag. The PAM was then easily prepared with the yield of 99.20 wt.% at 90 degrees C for 4 h with Ca/Si mole ratio of 0.75:1. According to Langmuir model, the adsorption capability of phenol on the PAM with a maximum uptake was 63.78 mg/g. According to adsorption thermodynamic results, the process was exothermic, thermodynamically feasible, spontaneous and chemically controlled. (C) 2015 Elsevier Ltd. All rights reserved.
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