期刊
RESULTS IN PHYSICS
卷 10, 期 -, 页码 956-963出版社
ELSEVIER SCIENCE BV
DOI: 10.1016/j.rinp.2018.08.012
关键词
Cerium; Hydroxyapatite; Transmission electron microscopy; Ultrasonic-assisted sol-gel technique; X-ray absorption near edge spectroscopy
资金
- Department of Chemistry (Faculty of Science)
- Research and Development Institute of the Udon Thani Rajabhat University (Thailand)
- National Research Foundation (NRF) of Korea through Ministry of Education [2016R1A6A1A03012812]
This present work focuses on the synthesis of cerium-doped hydroxyapatite (Ce/HAp-US) using an ultrasonic-assisted sol-gel technique under varying concentration of Ce from 0.5% to 2.0%. The preparative method utilized the stoichiometric molar ratio of Ca to P of 1.67 where the Ce/HAp samples were calcined at 600 degrees C for 2 h. The structural properties of Ce/HAp samples were characterized by various techniques including X-ray absorption near edge spectroscopy (XANES), X-ray powder diffraction (XRD), Fourier transform infrared spectroscopy (FT-IR), transmission electron microscopy (TEM) and energy dispersive X-ray spectroscopy (EDX). Results from the XANES spectra of xCe/HAp samples at the Ce L-3-edge reveal that the dominant species of cerium was Ce4+ along with some Ce3+, which have been incorporated into the HAp lattice. Results of the EDX analysis show that the Ca/P molar ratio of xCe/HAp decreased with an increase in Ce content. XRD analysis confirms that Ce3+ and Ce4+ were partially incorporated into the hexagonal framework of HAp and rhombohedral structure of beta-tricalcium phosphate (beta-TCP). FT-IR measurements identified the main functional groups of Ce/HAp to be hydroxyl (OH-), phosphate (PO43-) and carbonate (CO32-). The morphology obtained from TEM analysis illustrates that pure HAp-US is composed of very fine spherical particles. By incorporating Ce ions into the HAp lattice, the presence of dense dark spots, possibly the loaded Ce species, were observed.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据