期刊
ORGANIC CHEMISTRY FRONTIERS
卷 5, 期 20, 页码 2997-3002出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c8qo00887f
关键词
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资金
- 1000 Youth Talents Plan
- National Natural Science Foundation of China [21871166, 21402107]
- Natural Science Foundation of Shandong Province [ZR2018BB021]
A neutral cobalt(ii) compound Cp*Co(1,2-Ph2PC6H4S) (1, Cp* = Me5C5-) catalyzes the radical cyclization of 2-isocyano-biphenyls with alkyl halides, providing a variety of 6-substituted phenanthridines and phenanthridine-fused polycyclic compounds in good to excellent yields. The mild reaction conditions allow the catalysis to tolerate various alkyl halides for scaled-up syntheses. Polycyclic compounds with a 6-ethylpropanoate group at the C6 position can be hydrolyzed to provide the 6-ethyl substituted N-heterocycles, which exhibit useful emission properties upon protonation.
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