期刊
ORGANIC CHEMISTRY FRONTIERS
卷 5, 期 20, 页码 2986-2991出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c8qo00840j
关键词
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资金
- Key Science and Technology Program of Science and Technology Department of Henan Province [132102210042]
- Henan Agricultural University [KJCX2018A10]
A novel and regioselective thiolation reaction of aza-heteroaromatic N-oxides with disulfides via copper catalyzed C-H activation has been developed. The desired thioethers and selenide ethers were isolated in up to 90% yield and feature a very broad substrate scope. In addition, the C(sp(3))-H bonds of methyl-substituted aza-heteroaromatic compounds were also tolerated in this reaction and the corresponding dithioacetal products were obtained in moderate to good yields.
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