4.7 Article

Intermolecular reactions of gold(I)-carbenes with furans by related mechanisms

期刊

ORGANIC CHEMISTRY FRONTIERS
卷 1, 期 7, 页码 759-764

出版社

ROYAL SOC CHEMISTRY
DOI: 10.1039/c4qo00130c

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资金

  1. European Research Council [321066]
  2. MINECO [CTQ2010-16088/BQU]
  3. AGAUR [2009SGR47]
  4. EU Project ICT (ATMOL) [FP7-270028]
  5. ICIQ Foundation

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The intermolecular gold(I)-catalyzed reactions of propargyl carboxylates, 1,6-enynes, or 7-substituted 1,3,5-cycloheptatrienes with furans afford cyclopentenones, polyenes or polycyclic compounds by related mechanisms initiated by the electrophilic addition of gold(I) carbenes to furans followed by ringopening.

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