期刊
ORGANIC CHEMISTRY FRONTIERS
卷 1, 期 11, 页码 1280-1284出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c4qo00240g
关键词
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资金
- National Basic Research Program of China [2015CB931900]
- Syngenta PhD Fellowship
- National Natural Science Foundation [21032006, 21172240, 21421002, 21472222]
- Science and Technology Commission of Shanghai Municipality [14ZR1448800]
- Chinese Academy of Sciences
Copper-catalyzed tandem trifluoromethylation/cyclization of internal alkynes with Umemoto's reagent leads to 3-trifluoromethyl-1,2-dihydronaphthalene derivatives in moderate to good yields. The utility of this copper-catalyzed tandem reaction was demonstrated by oxidizing and reducing the trifluoromethylated product to give naphthalene and tetrahydronaphthalene, respectively, and the development of a short route to a trifluoromethylated analogue of Nafoxidine.
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