期刊
ORGANIC CHEMISTRY FRONTIERS
卷 1, 期 4, 页码 351-354出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c4qo00072b
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资金
- National Science Foundation [CHE-1316956]
- China Scholarship Council
A cyclic C-bromo-iminium bromide reacts with lithium trimethylsilyl acetylide to afford the title compound 2(+center dot) in 40% yield. In contrast to other organic mixed valence compounds, this radical cation can be stored in air. Oxidation and reduction of 2(+center dot) afford the corresponding dication 2(++) and neutral cumulene 2, respectively, in good yields.
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